Study of the Application of Polyolefin Elastomer (POE) Grafted Silane Coupling Agent in Photovoltaic Encapsulation Adhesive Film
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Keywords

Silane coupling agent KH-171
POE
Tensile strength
Breaking strength

DOI

10.26689/ssr.v6i3.6414

Submitted : 2024-02-29
Accepted : 2024-03-15
Published : 2024-03-30

Abstract

POE-g-KH-171 was prepared by twin-screw melt extrusion method, and the differences in the properties of POE-g-KH-171 prepared by using polyolefin elastomer (POE) as the substrate, different contents of DBPH, and different contents of coupling agent were explored. The grafting products were characterized qualitatively by Fourier infrared (FT-IR) spectroscopy, and the graft ratio and grafting efficiency of the products were determined. The performance of the adhesive was analyzed by a 180° peel strength test. The optimal content of vulcanizing agent was found to be 0.25, with the content of silane coupling agent KH-171 being 4. This composition achieved a graft ratio of 3.4, a grafting efficiency of 0.85, and a melt flow index of 12.98 g/10 min; the adhesion performance was excellent. The mobility of the product that was created with the optimum ratio of materials was then tested, followed by a comparative analysis with POE. The modified material (POE-g-KH-171) showed better performance than regular POE. Besides, POE-g- KH-171 had similar properties with ethylene-vinyl acetate (EVA) materials. This modified material is expected to mature in the future, contributing to the advancement of photovoltaic encapsulation technology.

References

Czanderna AW, Pern FJ, 1996, Encapsulation of PV Modules Using Ethylene Vinyl Acetate Copolymer as a Pottant: A Critical Review. Sol. Energy Mater. Solar Cells 43(2): 101–181.

Ndiaye A, Charki A, Kobi A, et al., 2013, Degradations of Silicon Photovoltaic Modules: A Literature Review. Sol. Energy 96: 140–151.

Kempe M, 2016, Encapsulant Materials for PV Modules, in Photovoltaic Solar Energy: From Fundamentals to Applications, Hoboken, 478–490.

Omazic A, Oreski G, Halwachs M, et al., 2019, Relation Between Degradation of Polymeric Components in Crystalline Silicon PV Module and Climatic Conditions: A Literature Review. Sol. Energy Mater. Solar Cells, 192: 123–133.

Pern FJ, 1996, Factors that Affect the EVA Encapsulant Discoloration Rate Upon Accelerated Exposure. Sol. Energy Mater. Solar Cells, 41–42: 587–615.

Pern FJ, Czanderna AW, 1992, Characterization of Ethylene Vinyl Acetate (EVA) Encapsulant: Effects of Thermal Processing and Weathering Degradation on its Discoloration. Sol. Energy Mater. Solar Cells, 25(1–2): 3–23.

Oreski G, Ottersböck B, Omazic A, 2019, 6-Degradation Processes and Mechanisms of Encapsulants. In Durability and Reliability of Polymers and Other Materials in Photovoltaic Modules, William Andrew Publishing, New York,

–152.

Weber U, Eiden R, Strubel C, et al., 27th European Photovoltaic Solar Energy Conference and Exhibition, Frankfurt, Germany, September 24–28, 2012: Acetic Acid Production, Migration and Corrosion Effects in Ethylene-Vinyl Acetate- (EVA-) Based PV Modules, 2992–2995.

Matsuda K, Watanabe T, Sakaguchi K, et al., 2012, Microscopic Degradation Mechanisms in Silicon Photovoltaic Module under Long-Term Environmental Exposure. Japanese Journal of Applied Physics, 51(10): 10NF07.

López-Escalante M, Caballero LJ, Martín F, et al., 2016, Polyolefifin as PID-Resistant Encapsulant Material in 5PV6 Modules. Sol. Energy Mater. Sol. Cells 144: 691–699.

Adothu B, Bhatt P, Chattopadhyay S, et al., 2019, Newly Developed Thermoplastic Polyolefifin Encapsulant–A Potential Candidate for Crystalline Silicon Photovoltaic Modules Encapsulation. Sol. Energy, 194: 581–588.

Adothu B, Bhatt P, Zele S, et al., 2020, Investigation of Newly Developed Thermoplastic Polyolefifin Encapsulant Principle Properties for the c-Si PV Module Application. J. Mater. Chem. Phys., 243: 122660.

Ottersböck B, Oreski G, Pinter G, 2017, Comparison of Different Microclimate Effects on the Aging Behavior of Encapsulation Materials Used in Photovoltaic Modules. Polym. Degrad. Stab. 138: 182–191.

Oreski G, Omazic A, Eder G, et al., 2020, Properties and Degradation Behavior of Polyolefifin Encapsulants for PV Modules. Prog. Photovolt. 28: 1277–1288.

Rashid MH, Yuan YX, 2017, Convergence Properties of a Restricted Newton-type Method for Generalized Equations with Metrically Regular Mappings. Appl Anal. https://doi.org/10.1080/00036811.2017.1392018

Ahmed N, Fan H, Dubois P, et al., 2019, Nano-Engineering and Micromolecular Science of Poly-Silsesquioxane Materials and their Emerging Applications. J Mater Chem A 7(38): 21577–21604. https://doi.org/10.1039/C9TA04575A