Keywords
Nanocomposites
Nylon
Polymer processing
Submitted : 2021-05-19
Accepted : 2021-06-03
Published : 2021-06-18
Abstract
Nylon 1212/organic montmorillonite (OMMT) nanocomposites were prepared using the melt compounding method. The morphology and dynamical mechanical properties of the nanocomposites were investigated using transmission electron microscope (TEM) and dynamic mechanical analysis (DMA). The storage modulus of nylon 1212/OMMT nanocomposites was increased with increasing OMMT. The flame retardant properties were characterized by cone calorimetry, scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). The flame retardant properties were characterized using cone calorimetry, whereby nylon 1212/OMMT nanocomposites were improved compared with pure nylon 1212 because of the carbonaceous-silicate granular materials which were formed during combustion, thus proposing the flame retardant mechanism.
References
Wang D, Parlow D, Qiang Y, et al., (2001), PVC?clay nanocomposites: Preparation, Thermal and Mechanical Properties[J]. Journal of Vinyl and Additive Technology, 7(4):203-213.
Usuki A, Kojima Y, Kawasumi M, et al., (1993), Synthesis of Nylon 6-Clay Hybrid[J]. Journal of Materials Research, 8(05):1179-1184.
Kord B, Malekian B, Ayrilmis N, (2017), Weathering Performance of Montmorillonite/ Wood Flour-Based Polypropylene Nanocomposites[J]. Mechanics of Composite Materials, 53(5):271-278.
Nan, Zhang, Ai-ling, et al., (2018), Effect of Liquid Crystal Ionomer Intercalated Montmorillonite Nanocomposites on PEO/PLA Solid Polymer Electrolytes[J]. Ionics, 16.
Wang X, Li Z, Zhang M, et al., (2017), Preparation of a Polyphenylene Sulfide Membrane from a Ternary Polymer/Solvent/Non-Solvent System by Thermally Induced Phase Separation[J]. RSC Advances, 7(17):10503-10516.
Follain N, Alexandre B, Chappey C, et al., (2016), Barrier Properties of Polyamide 12/Montmorillonite Nanocomposites: Effect of Clay Structure and Mixing Conditions[J]. Composites Science & Technology, 136(18):18-28.
Fornes TD, Hunter DL, Paul DR, (2004), Nylon-6 Nanocomposites from Alkylammonium-Modified Clay: The Role of Alky1 Tails on Exfoliation[J]. Macromolecules, 37(5):1793-1798.
Xing S, Li R, Si J, Tang P, (2016), In situ Polymerization of Poly(Styrene-Alt-Maleic Anhydride)/Organic Montmorillonite Nanocomposites and their Ionomers as Crystallization Nucleating Agents For Poly(Ethylene Terephthalate)[J]. Journal of Industrial & Engineering Chemistry, 38(25):167-174.
Wu Z, Zhou C, Na Z, (2002), The Nucleating Effect of Montmorillonite on Crystallization of Nylon 1212/Montmorillonite Nanocomposite[J]. Polymer Testing, 21(4):479-483.
Yu ZZ, Cheng Y, Yang M, et al., (2010), Mechanical and Dynamic Mechanical Properties of Nylon 66/Montmorillonite Nanocomposites Fabricated by Melt Compounding[J]. Polymer International, 53(8):1093-1098.
Priya L, Jog JP, (2003), Intercalated Poly(Vinylidene Fluoride)/Clay Nanocomposites: Structure and Properties[J]. Journal of Polymer Science Part B Polymer Physics, 41(1):31–38.
Tsagaropoulos G, Eisenberg A, (1995), Dynamic Mechanical Study of the Factors Affecting the Two Glass Transition Behavior of Filled Polymers. Similarities and Differences with Random Ionomers[J]. Macromolecules, 28(18):6067-6077.
Weyand S, Blattmann H, Schimpf V, et al., (2016), Structure-Property-Glass Transition Relationships in Non-Isocyanate Polyurethanes Investigated by Dynamic Nanoindentation[J]. Materials Research Express, 3(7):075019.
Jin Z, Start P, Mauritz KA, (2002), Thermal Stability and Flame Retardancy of Poly(Methyl Methacrylate)-Clay Nanocomposites[J]. Polymer Degradation & Stability, 77(2):253-258
Wang S, Yuan H, Zong R, et al., (2004), Preparation and characterization of flame retardant ABS/montmorillonite nanocomposite[J]. Applied Clay Science, 25(1-2):49-55.
Kashiwagi T, Jr R, Xin Z, et al., (2004), Flame Retardant Mechanism of Polyamide 6–Clay Nanocomposites[J]. Polymer, 45(3):881-891.
Song JB, Ren MQ, Chen QY, et al., (2004), Determination of Degree of Crystallinity of Nylon 1212 by Wide-angle X-ray Diffraction[J]. Chinese Journal of Polymer Science (English Edition), 22(5):491-496.
Wu Z, Zhou C, Na Z, (2002), The Nucleating Effect of Montmorillonite on Crystallization of Nylon 1212/Montmorillonite Nanocomposite[J]. Polymer Testing, 21(4):479-483.
Ren M, Song J, Song C, et al., (2005), Crystallization Kinetics and Morphology of Poly(Butylene Succinate-Co-Adipate)[J]. Journal of Polymer Science Part B: Polymer Physics.
Agag T, Koga T, Takeichi T, (2001), Studies on Thermal and Mechanical Properties of Polyimide–Clay Nanocomposites[J]. Polymer, 42(8):3399-3408.
Wang D, Parlow D, Yao Q, et al., (2010), PVC-clay Nanocomposites: Preparation, Thermal and Mechanical Properties [J]. Journal of Vinyl & Additive Technology, 7(4):203-213.
Kojima Y, Usuki A, Kawasumi M, et al., (2010), Novel Preferred Orientation in Injection?Molded Nylon 6?Clay Hybrid[J]. Journal of Polymer Science Part B Polymer Physics, 33(7)
Qin H, Zhang, et al., (2005), Flame Retardant Mechanism of Polymer/Clay Nanocomposites based on Polypropylene[J]. Polymer London.
Yong T, Yuan H, Lei S, et al., (2006), Preparation and Combustion Properties of Flame Retarded Polypropylene–Polyamide-6 Alloys[J]. Polymer Degradation & Stability, 91(2):234-241